silicious adj : relating to or containing or resembling silica; "gritrock is siliceous sandstone" [syn: siliceous]

English

Adjective

silicious

1. alternative spelling of siliceous

The chemical compound silicon dioxide, also known as silica or silox (from the Latin "silex"), is an oxide of silicon, chemical formula , and has been known for its hardness since the 9th century. Silica is most commonly found in nature as sand or quartz, as well as in the cell walls of diatoms. It is a principal component of most types of glass and substances such as concrete.

Manufactured forms

Silica is manufactured in several forms including:

• glass (a colorless, high-purity form is called fused silica)
• synthetic amorphous silica
• silica gel (used e.g. as desiccants in new clothes and leather goods)

It is used in the production of various products.

• Inexpensive soda-lime glass is the most common and typically found in drinking glasses, bottles, and windows.
• A raw material for many whiteware ceramics such as earthenware, stoneware and porcelain.
• A raw material for the production of Portland cement.
• A food additive, primarily as a flow agent in powdered foods, or to absorb water (see the ingredients list for).
• The natural ("native") oxide coating that grows on silicon is hugely beneficial in microelectronics. It is a superior electric insulator, possessing high chemical stability. In electrical applications, it can protect the silicon, store charge, block current, and even act as a controlled pathway to allow small currents to flow through a device. At room temperature, however, it grows extremely slowly, and so to manufacture such oxide layers on silicon, the traditional method has been the deliberate heating of silicon in high temperature furnaces within an oxygen ambient (thermal oxidation).
• Raw material for aerogel in the Stardust spacecraft
• Used in the extraction of DNA and RNA due to its ability to bind to the nucleic acids under the presence of chaotropes.
• Added to medicinal anti-foaming agent, like Simethicone, in a small proportion to enhance defoaming activity.
• As hydrated silica in Toothpaste (abrasive to fight away plaque.)

Health effects

Inhaling finely divided crystalline silica dust in very small quantities (OSHA allows 0.1mg/m3) over time can lead to silicosis, bronchitis or (much more rarely) cancer, as the dust becomes lodged in the lungs and continuously irritates them, reducing lung capacities (silica does not dissolve over time). This effect can be an occupational hazard for people working with sandblasting equipment, products that contain powdered silica, and so on. But children, asthmatics of any age, allergy sufferers and the elderly, all of whom have reduced lung capacity, can be affected in much shorter periods of time.

In all other respects, silicon dioxide is inert and harmless. When silica is ingested orally, it passes unchanged through the gastrointestinal tract, exiting in the feces, leaving no trace behind. Small pieces of silicon dioxide are equally harmless, as long as they are not large enough to mechanically obstruct the GI tract, or jagged enough to lacerate its lining. Silicon dioxide produces no fumes and is insoluble in vivo. It is indigestible, with zero nutritional value and zero toxicity.

Chemistry

Silicon dioxide is formed when silicon is exposed to oxygen (or air). A very thin layer (approximately 1 nm or 10 Å) of so-called 'native oxide' is formed on the surface when silicon is exposed to air under ambient conditions. Higher temperatures and alternate environments are used to grow well-controlled layers of silicon dioxide on silicon, for example at temperatures of 600 -1200 °C so-called "dry" or "wet" oxidation using O2 or H2O respectively. The thickness of the layer of silicon replaced by the dioxide is 44% of the thickness of the silicon dioxide layer produced.

• Low temperature oxidation (LTO) of silane

SiH4 + 2O2 → SiO2 + 2H2O (at 400-450 °C)

• Decomposition of tetraethyl orthosilicate (TEOS) at 680 – 730°C

Si(OC2H5)4 → SiO2 + H2O + 2C2H4

• Plasma enhanced chemical vapour deposition using TEOS at approximately 400°C

Si(OC2H5)4 + 12O2 → SiO2 + 10H2O + 8CO2

Pyrogenic silica(sometimes called fumed silica or silica fume), which is a very fine particulate form of silicon dioxide, is prepared by burning SiCl4 in an oxygen rich hydrocarbon flame to produce a "smoke" of SiO2:

SiCl4 + 2H2 + O2 → SiO2 + 4HCl

Quartz exhibits a maximum solubility in water at around 340 °C . This property is used to grow single crystals of quartz in a hydrothermal process where natural quartz is dissolved in superheated water in a pressure vessel which is cooler at the top. Crystals of 0.5 -1 kg can be grown over a period of 1-2 months. these crystals are a sourcer of very pure quartz for use in electronic applications. The change in the coordination increases the ionicity of the Si-O bond. Note that the only stable form under normal conditions is α-quartz and this is the form in which crystalline silicon dioxide is usually encountered. |- |fibrous | orthorhombic | like SiS2 consisting of edge sharing chains | |}

Molecular forms of silicon dioxide

When molecular silicon monoxide, SiO is condensed in an argon matrix cooled with helium along with oxygen atoms generated by microwave discharge molecular SiO2 is produced which has a linear structure. The Si-O bond length is 148.3 pm which compares with the length of 161 pm in α-quartz. The bond energy is estimated at 621.7 kJ/mol. Dimeric silicon dioxide, (SiO2)2 has been prepared by reacting O2 with matrix isolated dimeric silicon monoxide, (Si2O2). In dimeric silicon dioxide there are two oxygen atoms bridging between the silicon atoms with an Si-O-Si angle of 94° and bond length of 164.6 pm and the terminal Si-O bond length is 148.2pm.

Notes

References

• R. K. Iler, The Chemistry of Silica (ISBN 0-471-02404-X)

See also

• Amorphous carbonia
• Fused silica
• Silicon carbide
• Mesoporous silica

External links

• (Tridymite)
• (Quartz)
• (Cristobalite)
• NIOSH Pocket Guide to Chemical Hazards (amorphous)
• NIOSH Pocket Guide to Chemical Hazards (crystalline, as respirable dust)
• Quartz SiO2 piezolelctric properties